Novel Nb<sup>5+</sup>-doped hexagonal perovskite Ba<sub>5</sub>In<sub>2</sub>Al<sub>2</sub>ZrO<sub>13</sub> (structure, hydration, electrical conductivity)
نویسندگان
چکیده
The new phase Ba5In2Al2Zr0.9Nb0.1O13.05 with hexagonal perovskite structure was obtained. substitution of Zr4+ by smaller Nb5+ accompanied the incorporation oxygen interstitials and did not lead to a significant change in lattice parameters. It established that investigated sample capable for water from gas phase, hydration degree value 0.24 mol H2O. IR-spectroscopy analysis defined presence OH−-groups different thermal stability, which participate hydrogen bonds. demonstrates predominant protonic conductivity at pH2O = 2·10−2 atm Т600 °C.
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ژورنال
عنوان ژورنال: Chimica techno acta
سال: 2022
ISSN: ['2411-1414', '2409-5613']
DOI: https://doi.org/10.15826/chimtech.2022.9.4.14